Graham's DIffusion Law

IMPORTANT

Graham's DIffusion Law: Overview

This topic covers concepts, such as, Diffusion of Gases, Graham's DIffusion Law, Effusion of Gases & Applications of Graham's Diffusion Law etc.

Important Questions on Graham's DIffusion Law

EASY
IMPORTANT

Two gases A and B having the same volume diffuse through a porous partition in 20 and 10 seconds respectively. The molecular mass of A is 49 u. Molecular mass of B will be:

EASY
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From a heated mixture of nitrogen, oxygen and carbon, two compounds (out of the many obtained) are isolated. The rates of diffusion of the two isolated compounds are almost identical. The two compounds are

HARD
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Pure O2 diffuses through an aperture in 224 sec, where as mixture of O2 and another gas containing 80% O2, diffuses from the same in 234 sec. What is molecular weight of the gas.

MEDIUM
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A gas mixture contains equal number of molecules of N2 and SF6, some of it is passed through a gaseous effusion apparatus. Calculate how many molecules of N2 are present in the product gas for every 100 molecules of SF6.

MEDIUM
IMPORTANT

From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3 s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.

MEDIUM
IMPORTANT

From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3 s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.(Oxygen/Nitrogen)

HARD
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The degree of dissociation α of the reaction A2g2Ag  in terms of rate of diffusion rmix of equilibrium mixture and that of a reference gas C is given by: 

where M stands for the respective molar masses.

MEDIUM
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In 5 s, the volume Xof H2 gas effuses through a hole in a container. The time taken for the effusion of the same volume of the specified gas under identical conditions is

MEDIUM
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Heg at 1 atm and O2g at 4 atm pressure are effused through a small orifice under similar conditions, ratio of their rate of effusion is -

EASY
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Molar ratio in which He and CH4 should be mixed so that when mixture is allowed to effuse through pinhole, initially both gases comes out at equal rate? 

MEDIUM
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50 mL of each gas A and of gas B takes 150 and 200 seconds respectively for effusing through a pin hole under the similar conditions. If molecular mass of gas A is 36, the molecular mass of gas B will be :

MEDIUM
IMPORTANT

A gas is effusing in vacuum at rate r1 and in air at rate r2, then :

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HARD
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Calculate relative rate of effusion of O2 to CH4 through a container containing O2 and CH4 in 3:2 mass ratio :-

EASY
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The rate of diffusion of CH4 at a given temperature is twice that of a gas X. The molecular weight of X is :-

EASY
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At constant pressure and temperature the rates of diffusion rA and rB of gases A and B having densities dA and dB are related as :-

MEDIUM
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The molecular weight of a gas which diffuses at 1/6th  of the speed of hydrogen under identical conditions is :-

MEDIUM
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Which pair of the gaseous species diffuse through a small jet with the same rate of diffusion at same P and T :-

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If the rate of diffusion of unknown gas is twice that of methane gas under identical condition of temperature and pressure, the molar mass of the unknown gas is

MEDIUM
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Four gas balloons A, B, C, D of equal volumes containing H2, H2O, CO, CO2 respectively were pricked with needle and immersed in a tank containing CO2 at same pressure which of them will not shrink after some time :

MEDIUM
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A certain gas diffuses from two different vessels A and B. The vessel A has a circular orifice and vessel B has square orifice and radius of the orifice of vessel A is equal to side of orifice of vessel B. The ratio of rate of diffusion of gas from vessel A to vessel B, assuming same temp and pressure is.